Chemical Oxygen Demand or Need Oxygen chemistry is amount oxygen is needed for waste organic matter in the water can? oxidized in a way chemistry . Chemical Oxygen Demand (COD ) have the value which is size For level pollution by material organic . COD value contained in material standard such as palm oil mill effluent can converted into biogas due to its high value so that allow For produce high biogas production . On study This done data collection in direct that is with using secondary data and primary data. From the research that has been done , known that The more high COD Removal then the more The quality of the methane gas produced is also high . This is can seen based on at COD removal of 81%, it was obtained methane gas quality by 67%. And, increasingly high COD lowered so the more The biogas production produced is also high . This is can seen based on on COD reduction of 797,716 kg resulted in biogas production of 478,629 m3.